How
do solar cells work?
There
are really only two possible endpoints for human energy production, and they’re
both fusion. Either we find a way to create tiny,
controlled fusion reactions here on Earth (fusion power) or we find a
way to usefully collect a good portion of the energy already being released
form the enormous fusion reactor our solar system has built right
in (solar power). The nice thing about the solar option is that it can
come about incrementally, giving us partial utility while inching ever-closer
to the tipping point, when it could provide for the majority of
our electrical needs. But what is a solar cell, the centrally important
component of solar power, and how does it work?
A
solar cell, also called a photovoltaic cell, is defined as any device that can
capture some of the energy of a photon of light, and pass that energy on to a
device or storage medium in the form of electricity. Not all solar power
is photovoltaic in nature, as some solar technologies collect the heat of
absorbed photons, rather than their energy, directly. Still, with such a
general definition, the term photovoltaic’s encompasses a wide variety
of different technologies.
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All
of them have one thing in common, however: they use the energy of a photon
to excite electrons in the cell’s semi-conducting material from a
non-conductive energy level to a conductive one. What makes this complex
is that not all photons are created equal. Light arrives as an unhelpful
amalgamation of wavelengths and energy levels, and no one semi-conducting
material is capable of properly absorbing all of them. This means that to
increase the efficiency of capture of solar radiation, we have to make
hybrid (“multi-junction”) cells that use more than one absorbing material.
Each
semi-conducting material has a characteristic “band gap” or a spectrum of
electron energies which the material simply cannot abide. This gap lies between
the electron’s excited and unexcited states. An electron in its rest state
cannot be excited into usefulness unless it receives enough excess energy to
jump right over this band gap. Silicon has a nice, achievable band
gap, one that can be bridged by a single photon’s-worth of extra energy.
This allows silicon to be nicely either on (conducting) or off (not), as
defined by the position of its potentially conductive electrons.
A
material like graphene could,
in one sense, be a far better basis for a photovoltaic cell than
silicon due to its incredible electrical efficiency and the potential to
be packed far more densely on the panels themselves — the big problem comes
back to the band gap, and graphene’s inability to be properly excited by the
power of an incoming photon. Some complex graphene devices like dual gate
bilayer graphene transistors — but the problems with
actually manufacturing such devices offset the potential gains, at
least for now.

Anti-reflective
coatings increase the amount of light absorbed overall, while chemical
“doping” of the transistors themselves can improve silicon’s optical
abilities. Some solar setups use fields of mirrors to concentrate as much solar
radiation as possible on just a few high-capacity cells at the center. Many are
now even designed as light-capture devices, so light that enters gets bounced
around internally, forever, until it’s all eventually absorbed. Last fall,
researchers at the University of Michigan even developed a fully transparent solar
cell.
Heat
may also be an increasingly important part of solar power rigs, since any
radiation not electronically absorbed will at least be partially absorbed as
raw heat. Using this heat to boil water, or even heat homes directly,
could help civilian solar power improve overall efficiency even while
electrical super-materials continue to play catch-up.
Even
more out-there concepts, like space-based solar power, offer some potential by
capturing light before it’s filtered through the Earth’s atmosphere; Japan
wants to generate a gigawatt of solar power in space, for instance. The problem
is getting the power down to the surface, where it could be useful to human
beings. The Japanese initiative looks to use lasers for that purpose, but
there’s no telling whether bypassing the atmosphere will prove to be a winning
strategy, overall.
Solar
cells have been hamstrung by several decades of premature headlines announcing
such a winning overall strategy and the oncoming dominance of solar
power. The reality is that there will almost certainly never be any such
eureka moment in engineering. Solar cell technology will be amended and
upgraded until it passes some abstract threshold based on affordability, the
state of power storage and transmission technology, and the local annual level
of sunlight.
All
types of solar power will be important to any real attempt to roll out green
power on a national scale. Unless fusion makes huge leaps forward, or classical
nuclear power becomes a whole lot more popular, you can bet that solar will be
a big part of our energy future.
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